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Nov. 09, 2022

BIDR's environmental physicist Prof. Arik Yochelis​ and Technion – Israel Institute of Technology material scientist Prof. Avner Rothschild took a different tack and believe they have identified new pathways to speed up the catalytic process is expected to reduce the invested electrical energy costs significantly.

Right to left: Prof. Arik Yochelis and Prof. Avner Rothschild | Photo Credit: Courtesy
Right to left: Prof. Arik Yochelis and Prof. Avner Rothschild | Photo Credit: Courtesy

Oxygen evolution requires the transfer of four electrons to create one oxygen molecule (O2) and two hydrogen molecules (H2). According to the current paradigm, those electrons move one after the other in a sequence of four steps on an atomic reaction site, which makes the chemical reaction energetically difficult. The water-splitting process aided by solar energy (i.e., photoelectrochemistry) lowers the amount of the invested electrical power needed to break the chemical bonds in the water molecule to generate hydrogen and oxygen.

However, Profs. Yochelis and Rothschild showed, theoretically and experimentally, a new paradigm in which two electrons can simultaneously be transferred at different reaction sites, reducing the energy barriers for oxygen evolution.

They were initially troubled by experiments that did not fit the existing paradigm and so set out to find a different rationale.

Their findings were published in the top journal in the sustainability Energy & Environmental Science field.

"Our research changes the common understanding within the scientific community regarding the catalytic mechanism for oxygen evolution, a central and important reaction that represents a bottleneck in producing hydrogen from water. Combining knowledge and experience from two fields showed that the catalytic reaction is more complicated than people think. Hopefully, this new understanding will lead to additional breakthroughs in materials development and new processes to create clean fuels from renewable resources to facilitate the transition to net zero," says Prof. Rothschild.

"Over and above the scientific contribution of the research, it is important to emphasize the importance of the multidisciplinary approach and collaborations when dealing with complex systems like the energy system. This would not have happened without open-minded and constructive communication between researchers with different approaches. It is a lesson to all; frank collaboration will always yield creative 1` solutions to challenging problems," Prof. Yochelis adds.

Prof. Yochelis is a faculty member of the Jacob Blaustein Institutes for Desert Research in Sde Boker at BGU, and Prof. Rothschild is a faculty member of the Materials Science and Engineering Department at the Technion. The study was supported by the Israeli Ministry of Science and Technology (grant no. 3-14423) and conducted mainly by Ph.D. student Anton Tsyganok (Technion) and postdoctoral fellow Dr. Paulino Monroy-Castillero (BGU).

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